TEAM 1 (Crafting/Dugeon Team)
Death Knight (Blood/Unholy) Blacksmithing/Enchanting
Shaman (Resto/Elemental) Alchemy/Leatherworking
Warlock (Demo/Destro) Inscriptions/Tailoring
Mage (Fire/Frost) Jewelcrafting/Tailoring
Hunter (BM/Marks) Engineering/Leatherworking

TEAM 2 (Farming/Funsies)
Demon Hunter (TANK) Enchanting/Skinning
Monk (Mistweaver) Herbalism/Mining
Rogue (Outlaw) Herbalism/Mining
Shaman (Enhancement) Herbalism/Mining
Warrior (Fury) Herbalism/Mining

I call this my division of labor strategy, initially my main team will be Mining in place of their armor profession. I will be selling ore and stocking up on Bloods for the first week or two. Then, I'll switch mining for Smithing, Leatherworking, and Tailoring respectively. Then of course I can switch to team two to farm mats to feed the main team.