By Default Shift+Alt+R toggles mouse and keyboard broadcasting (Repeater) on and off. You can, off course, change this Hotkey to whatever you like.
For Diablo III, unlike for other games, it is normal to have Repeater on most of the time. This is addressed specifically in the Quick Start Guide for Diablo III. If you need to move your characters back together, briefly toggle Repeater off, click on your secondary character to restack them, and then turn Repeater back on again.
There has been considerable discussion of more advanced techniques on the ISBoxer Diablo III forum.
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