I first passed (with HotKeyNet) ALT-SHIFT-A thru ALT-SHIFT-P, but they did the actions that A thru P did. If you don't have a key specifically defined, the normal unmodified key gets used. So you need to map the CTRL-Char and ALT-Char keys to do something or they just get used as the Char keys.

For spinning around. I use 2 effects. I use all alts backup and every char spin around. The backup is just alts get 's' and main gets nothing. For spin around, I use left and right arrow keys. If I get a rogue on me on my hunters, I just have alts backup and my main move forward. It gives enough room for shoot and leads the jerk away from my more squishy hunters (I load up on stam on my main for BG's---cause all the forum kiddies say, kill the leader).