You need to check the ema settings on each and every character. If the teamlist is correct and it shows your main toon as the leader, while the others are slaves, they should get the settings sent from other characters. Worst case scenario, then also tick the "use guild communications", then retry.. if they are in the same guild.
Basically you have to "confirm group etc" on each character, in order to "automatically accept requests"... or else you could risk getting requests sent by complete strangers.
What i do: invite the characters into the party / raid. Then from main character "add players in group/raid" to my list. Then do the same on the slaves. Then at the end i send one final settings to all from my main. You will see in the slaves chatboxes if they recieved it or not.
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