The thing is, you're going to have a harder time mining only scordite in hisec because there will be less spawns, and more people competing for the ore. My hisec mining experience is minimal, but I don't doubt that miners there cherry pick the scordite from the start. Its better to mine in null because you get higher concentrations of the valuable ore, and you don't have to compete for the ore. I don't mind going in to further detail if you'd like.
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