As a beginning multiboxer you should forget about trying to box melee characters because they are harder to multibox (especially the rogue) - skip the rogue and warrior unless that is your tank and go with three ranged dps + healer + tank.
Granting levels works only on the account that invited some other account so it depends how you distribute the invitations for your team. Most people go with A -> B -> C -> D -> E because that way you can grant levels to additional toons on each account (well all but the last one) and transfer one or two toons from A to E after raf ends.
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