Thank you both Jason and Aradar for your help and feedback, it's very nice of you to take the time. But I was too vague (what I get for posting after midnight)

Clarification is that I want to make use of the majority of those teams. Maybe assemble at least 4 -5 teams with those people, so that I can get as many of those to 80 as possible so that I can begin cranking out a massive number of easy to do dailies.

With that in mind, how would you assemble the teams so that the most number of toons get used and that all teams are viable? That's where I'm getting a bit stumped. :/ (my goal is to speed up the grind for these characters to 80, not to complete the instances as I'm sure that will come in time. But trying to level up all of these toons to 80 without the exp boosts that come from the collection quests is like watching paint dry, only slightly less fun.)