Wont work off hand. Its a great program however it does not currently allow for full directx and 3d rendering.

There is a way to achieve it slightly though. If the game can run in linux and you download the VMGL I think (VM ogl drivers) you can run select games through linux, through the virutal machine.

So it is possible, but 90% of games wont work because if you use windows, it has no 3d rendering to support high end games.