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I would go frost mage. Starfire takes a long time to cast and a frost mage would be great to help him get an extra one or 2 off. Not to mention evocation,innervate, ports, food/drink, hella CC.
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Depends a little bit on what you are wanting to do with the combo IMO. Generally I like boxing hybrids for the multitude of combinations this allows. Given that you already have a druid which could heal/tank in a pinch, I think adding a good PvP dps class would give you the best flexibility. Caster/caster will be the easiest for you so I would pick a warlock.
I like the way afliction locks play in PvP, very mobile dps, good survivability with self heals and eventually soul link, and instant group fear. The druid would complement this well with a couple of good dots of their own, plus thr armour of moonkin.
For PvE stuff a demo lock may be a better match, using the pet as a light tank and switching to bear for heavier stuff.
If you can handle a melee/caster combo then I would pick a pally. Excellent survivability, ret pally's can tank fine up until level 60ish and put out a crapload of dps whilst still offering your caster a few buffs.
Hope that helps.
Cheers
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lock is a good pick indeed. Caster aswell, good synergy + pet can tank.
Anything you like can be done.
