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Not sure about what you suggest, but you could make an end-boss game with your main and invite the level 1's in - they complete and now have access to story mode and I think torment levels
You could even have them leave the game after being invited in - have of them resume it, and invite everyone back in for a level 1 boss fight - I THINK :)
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Just do the Act IV: "Clear the Hell Rift" bounty runs. It's the fastest EXP right now.
Asuming you have 4 accounts with at least 1 lvl70 char in each, and u want to boost new chars on each to 70:
- Create a Torment VI game on each lvl70 char (no party).
- Check on each character if u have the quest (just mouseover the list of bounties for Act IV).
- If no character has the quest, leave game and create a new one until you get it on any char.
- Once u have the quest, have all other chars join that game.
- Leave game on all the characters (max 3) u wanna power level and switch them to low level chars, but leave them in the lobby.
- With the lvl70 left ingame, rush thru Hell Rift lvl1 (dont kill anything) and go lvl2. Clear everything but a couple white mobs. It's very easy since all are white mobs. Every once in a while u will get a purple unique boss which is not hard to kill, but if u are too weak, u might wanna lower the difficulty.
- Once u have just a few mobs left, join game with the 3 chars u wanna power level and teleport to the lvl70 char.
- Kill the last mobs in lvl2. That will give u the bounty reward for all your chars. With pools at lvl70 its 80m exp and like 420k gold.
I've done all my chars/classes like this in just a day. It's very easy and fast to do. U gain a ton of exp and also gold. Sometimes u can get a Cursed Chest which can be as easy as killing 5 white mobs or 3 elites. If u get the elites, just leave game. It gives like 20m more exp.