Okay I'm in the bios and in one part - ASUSTeK EZ Flash 2 BIOS ROM Utility v3.37 it has three drives listed. C, D, E.
In my computer E has always been my SSD drive and D my DVD drive until this problem. In this utility it has C: as my main drive and when I load it I see all the programs it lists. It has D: as my SSD drive and when I load it it show WoW and InnerSpace. It has E: Optiarc DV which had nothing in it when I tried to load it due to nothing in the DVD drive. I put in a data disk and it shows it and loads it and you can see the files on the disk. When I click on "Drive Info" for this volume it says: Drave Name: Optiarc DVD RW AD-7200A (I assume that's my DVD drive brand and model).
So not sure what any of that means.
In Boot Device Priority it shows the Optiarc DVD as the #1 boot option, then my hard drive as the 2nd option.